If a person chooses to walk rather than drive, there is one less vehicle emitting pollution into the air than there would be otherwise.
Conclusion (Therefore)
If people would walk whenever its' feasible, pollution will be greatly reduced.
Evidence
If someone chooses to walk rather than drive, there will be one less vehicle emitting pollution into the air.
Evaluate
Both the premise and the conclusion are conditional, but the conversation somehow doesn't seem like it's meant for conditional "missing link" thinking. The author is making a prediction, and predictions are inherently Comparisons: we're comparing our current world to this hypothetical future world.
In this hypothetical world, what sort of comparisons is the author assuming?
She's thinking that people will walk more than they used to and drive less than they used to (overall). And she thinks the emissions caused by "walking, not driving" will be lower than the emissions that would have resulted from "driving".
How could we object to this argument? Can we think of some storyline where we're in this hypothetical world where people walk whenever it's feasible, but somehow pollution has not been greatly reduced?
Will people be creating pollution that wouldn't have existed otherwise by walking?
- maybe they start smoking more, and the smoke pollutes - maybe the walking makes them fart more, and that methane is a greenhouse gas (not a likely LSAT answer) - maybe they use electrical devices more to listen to podcasts, and the pollution involved in increased demand for those products is worse than the pollution that would be caused by driving
Importantly, though, because the prediction is "pollution will be significantly reduced", not just "pollution will be reduced", we don't have to come up with a story where people's emissions from walking are worse than those from driving.
Even if the new emission are just somewhat significant, they could offset a lot of the emissions savings the author thinks we're getting by not driving. That would still allow us to argue that the net effect of walking whenever feasible has not been a significant reduction.
Goal
Tough to know what to predict. Look for something that matches something the author is clearly thinking, probably relating to a Comparison between our current world and the hypothetical world.