If a person chooses to walk rather than drive, there is one less vehicle emitting pollution into the air than there would be otherwise.
Conclusion
If people walked whenever feasible, pollution would be greatly reduced.
Evidence
When someone chooses to walk rather than drive, there's one less vehicle emitting pollution into the air than there would be otherwise.
Evaluate
This argument is based on a Comparison between the "walk whenever possible world" and the actual world.
We know one difference: When people walk instead of driving, there's one less vehicle emitting pollution than otherwise, but what else might be different (that would affect pollution)?
Does someone who chooses to walk instead of drive start doing something new that adds to pollution? (maybe because they're walking they choose to smoke, and that leads to pollution .... maybe they have to buy walking shoes more frequently, and the production of rubber soles leads to pollution)
These are pretty unlikely objections, but any answer that rule out the idea that walking created new forms of pollution would be useful.
The other vulnerability of the argument is that the author thinks the difference between the walk-when-possible world and the actual world is that in the former, pollution will be greatly reduced.
We might freely admit that pollution will be lessened by walking instead of driving, but disagree that it will be a great / significant reduction.
So if an answer helped to convince us that this could lead to GREAT reductions in pollution, that would also work.
Goal
Look for an answer ruling out some idea that walking instead of driving creates a new form of pollution, or for an answer making it seem like car pollution is a BIG contributor to pollution or that people are FREQUENTLY driving instead of walking, so that in a walk-when-possible world there would be a big difference in pollution.